As a user, you will invoiced for your product / service purchases the same way that you're invoiced for any other additional charges. It is dependent on how your organization has set up invoices. You will either be invoiced the day of purchase, or it will be added to your next month’s invoice. Purchases can also be added onto your team's invoice.
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You can review your purchases much like any other invoice (read how to review invoices here).
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Please reach out to your organization's administrator if you have any further questions.